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We undertook Zr isotope measurements on zircon, titanite, biotite, amphibole, and whole rocks from the La Posta pluton (Peninsular Ranges, southern California) together with trace element analyses and U-Pb age measurements to understand the controls on Zr isotope fractionation in igneous rocks, including temperature, crystallization sequence, and kinetic effects. We find large (>0.6‰) Zr isotope fractionations (expressed as δ94/90Zr) between titanite and zircon forming at approximately the same temperature. Using equilibrium fractionation factors calculated from ionic and ab initio models, we infer the controls on Zr isotope evolution to include the relative order in which phases appear on the liquidus, with titanite fractionation resulting in isotopically lighter melt and zircon fractionation resulting in isotopically heavier melt. While these models of Zr fractionation can explain δ94/90Zr variations in zircon of up to ∼1.5‰, crystallization order, temperature and presence of co-crystallizing phases do not explain all aspects of the intracrystalline Zr isotopic distribution in zircons in the La Posta pluton or the large range of Zr isotopic values among zircons (>2‰). Without additional constraints, such as knowledge of co-crystallizing phases and a better understand of the true causes of Zr isotope fractionation, Zr isotopes in zircon remains an ambiguous proxy of magmatic evolution. 

Tectonic deformation can influence spatiotemporal patterns of erosion by changing both base level and the mechanical state of bedrock. Although base-level change and the resulting erosion are well understood, the impact of tectonic damage on bedrock erodibility has rarely been quantified. Eastern Tibet, a tectonically active region with diverse lithologies and multiple active fault zones, provides a suitable field site to understand how tectonic deformation controls erosion and topography. In this study, we quantified erosion coefficients using the relationship between millennial erosion rates and the corresponding channel steepness. Our work shows a twofold increase in erosion coefficients between basins within 15 km of major faults compared to those beyond 15 km, suggesting that tectonic deformation through seismic shaking and rock damage significantly affects eastern Tibet erosion and topography. This work demonstrates a field-based, quantitative relationship between rock erodibility and fault damage, which has important implications for improving landscape evolution models. 

The time of origin of the geodynamo has important implications for the thermal evolution of the planetary interior and the habitability of early Earth. It has been proposed that detrital zircon grains from Jack Hills, Western Australia, provide evidence for an active geodynamo as early as 4.2 billion years (Ga) ago. However, our combined paleomagnetic, geochemical, and mineralogical studies on Jack Hills zircons indicate that most have poor magnetic recording properties and secondary magnetization carriers that postdate the formation of the zircons. Therefore, the existence of the geodynamo before 3.5 Ga ago remains unknown.